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I loko o kēia hana,ʻo RGO / NZVINANDER PERSPERITED no ka manawa mua e hoʻohana ana i ka huiʻo Spoting Ua hoʻohanaʻia kekahi mau mea hana e hōʻoia i ka synthes o ka huiʻana, e like me Sem, edx, xps, xps, xps ʻO ka hikiʻana o ka weheʻana o nā hua'ōlelo novel a me ka nzviʻo nzvi i nāʻano likeʻole e like me nā mea hoʻohālua antibiotic ma waena o Rgo a Nzvi. Ma lalo o nā kūlana o nā hoʻololi o 25MG L-1, 25 ° C a me 0.05g ka palenaʻo NZERattive o DOX / NVI. ʻO ke kaʻina hana AdSorple e pili ana i kahi kauoha Pseudo-ʻelua a me kaʻaeʻana i kaʻaeʻana i ka freditlich i ka pae o ka f-1 ma 25 °. Eia kekahi,ʻo ka hikiʻana o keʻano o ka RGO / NZVI BEPOSITE he 60% ma hope oʻeono mau hana hou.
ʻO ka wai inu wai a me ka haumia i kēia manawa he hoʻoweliweli koʻikoʻi i kēia mau'āina a pau. I nā makahiki i hala iho nei, haumia ka wai,ʻoi aku ka hoʻonuiʻana i ka maʻi antibiotic, ua hoʻonuiʻia ma muli o ka hoʻonuiʻiaʻana o ka hana covid-19. No laila,ʻo ka hoʻomohalaʻana o kahiʻenehana kūpono no ka hoʻopauʻana o nā antibiotics ma ka waiʻole o ka wai wai i ka hana nui.
ʻO kekahi o nā mea e kū ai i ka sui-synthetic antibiotics mai ka huiʻo Tetracyclineʻo Derxyclineʻo Docycycline (DC) 4,5. Ua hōʻikeʻiaʻo ia e pili ana i nā koena DC ma ka'āina a me nā wai waiʻole,ʻo 20-50% mau pilikia a me ke olakino.
Hōʻike ka hōʻikeʻana iā DC ma nā haʻahaʻa haʻahaʻa e pepehi i nā microorganisms photos ʻO keʻano kūlohelohe maoli o DC i ka wai ke kaʻina lohi loa. ʻO nā kaʻina hana lapaʻau-chinesical e like me ka photolysis, hiki i ka biodegradation a me ka adsorgradation a hiki i ka hoʻolaha wale nō i nā haʻahaʻa haʻahaʻa a me nā haʻahaʻa haʻahaʻa haʻahaʻa haʻahaʻa. Eia nō naʻe,ʻo kaʻoihana waiwai maikaʻi loa, maʻalahi,ʻoluʻolu, maʻalahi ke hoʻoponopono a hoʻoponoponoʻia keʻano kūpono a me keʻano kūpono.
ʻO Nano Vet Valle iron (NZVI) kahi mea ikaika loa e hiki ai ke wehe i nā antibiotika e hiki ai i nā antibalitics mai ka wai, e hui pū me ka chiprodcloxian, chiprolxolel Aia kēia hiki i kēia mau mea kupanaha loa e like me Nzvi, e like me keʻano kiʻekiʻe, he wahi ākea ākea, a me nā wahi nui o waho. Eia nō naʻe,ʻo NZVI ka mea e hoʻopili ai i nā hoʻolaha o ka marious ma muli o ka hanaʻana i nā mea hana o NZVIT o NZVIT.12. Hiki ke hoʻemiʻia ka aggolometion o nā'āpana NZVI e hoʻololiʻia e kā lākou mau papa me nā mea he nui a me nā potomers a iʻole e hui pū ana me nā mea'ē aʻe e hoʻomaikaʻi ai i ko lākouʻano
ʻO Criphene kahi carbon carbon carbonʻelua o nā carbon carbon e pili ana i ka cr2-hybridized carbon atoms i hoʻonohonohoʻia i loko o kahi lāʻau meli. He wahi nui o ka ma kahi ākea nui, nā ikaika nui loa,ʻo ka hana hou no ka hoʻohanaʻana, nā mea kaʻa kaʻaʻoi aku ka nui. ʻO ka hui pūʻana o nā nanopulartics metalarticles a me nā cripher eʻoi aku ka nui o nā pono o kēlā me kēia kanaka a me nā mea waiwai maikaʻi loa o Nanoport
ʻO nā mea kanu i nā mea maikaʻi loaʻo ia ke koho maikaʻi e hōʻemi i nā mea e hōʻemi ai i nāʻoihana maʻamau i hoʻohana pinepineʻia, a hiki ke hoʻohanaʻia e like me ka ho'ēmiʻana, a hiki ke hoʻohanaʻia e like me ka ho'ēmiʻana E like me nā flavolids a me nā mea pili phenolic e hana ai he stabilizer. No laila,ʻo Agriplex Halimple L. Leaf The Agectict as A Recporting And Komisina ʻO Atriplex Halimus mai kaʻohana Ammaranthaceae he Nitrogen-aloha BRURB
E like me ka palapala i loaʻa, atriplex Halima (A. HALLIMUS) mua e hana i keʻano o RGO / NZvi i keʻano o kaʻoihana. No laila,ʻo ka pahuhopu o kēia hana e loaʻa ana iʻehā mau'āpana: Loaʻa nā antixycline antibiotics ma lalo o nāʻanoʻano likeʻole, e hoʻopiʻi i nāʻano o ke kaʻina hoʻolaha o ka hoʻolahaʻana ma hope o ke kaʻina hanaʻana ma hope o ke kaʻina hana.
Dyxycycle hydrochloride (dc, mm = 480.90 Sodium hydroxide (Naoh, 97%), ethnol (c2h5oh Nacl, KCL, CALLL2, MNCL2 a me MGLL2 a me MGLL2 E kūʻaiʻia mai Tianjin Comity Comity Comity. Ua hoʻohanaʻia ka wai pāluaʻelua e hoʻomākaukau i nā hoʻonā āpau āpau.
ʻO nā Manaʻo Kahiki o A. HA Mumus i hōʻiliʻiliʻia mai ko lākou noho kūlohelohe ma ke poʻo NILE Delta a me nā'āina ma ke poʻo Meditererna ma kahakaiʻoʻAigupita. Ua hōʻiliʻiliʻia nā mea kanu e like me nā mea pili a me nā kulekele aupuni a me ke aupuni. Ua loaʻa iā Prof. Mal Fawzi i nā mea kanu lāʻau e like me ka poʻe hoʻomaloka o Alexandias i keʻano o nā kumuwaiwai Traintor. Ua mālamaʻia nā voucher somple ma ke kulanui o ke kulanui o Tanta University (Tane), Voucher Nos. 14 122-14 127, he kirbicurity he lehulehu e hoʻolako i nā mea komo i nā mea kūʻai aku. Eia kekahi, e wehe i ka lepo a iʻole lepo, eʻoki i nā lau o ka mea kanu i loko o nā'āpana liʻiliʻi, e maloʻo i ka wai a me ka maloʻo ma 50 ° C. Ua hoʻopauʻia ka mea kanu, 5 g o ka paula wahine maikaʻi loa i ka 100 ml o ka wai a me ka hōʻailona ma 7 min e loaʻa ai kahi'āpana. Ua kiʻiʻia ka mea i loaʻa iā Buchilus Nicotpaie e kiʻiʻia ma o ka pepa kānana a mālamaʻia i ka hoʻomaʻemaʻe a me nā mea hoʻomaʻemaʻe.
E like me ka hōʻikeʻana ma ke kiʻi 1, i hanaʻia mai keʻano o ka paila kiʻi e ka loli o nā mea hino. 10 mg o ka pauka e hoʻokaʻawaleʻia ma 50 ml o ka wai deionized no 30 min ma lalo o ka hānauʻana, a laila ua huiʻiaʻo fecc3 a me 2.9 g o Oac i huiʻia no 60 min. 20 ml o ka left leaf raditract i hoʻohuiʻia i ka hopena stictik i hoʻohuiʻia me ka hoʻouluʻana a me ka waihoʻana ma 80 ° C no 8 mau hola. Ua kiʻiʻia ka hopena o ka hopena o ka hopena. Ua holoiʻia nā makemake o ka makemake i nā wai ethanol a me nā wai a me ka bonistled a laila maloʻo i loko o kahi hakahaka i 50 ° C no 12 mau hola.
Nā kiʻi kiʻi kiʻi a me nā kiʻi paʻi kiʻi o ka synthesis'ōmaʻomaʻo o RGO / NZVI a me NZVI GRECHES A me ka weheʻana o ka wai i loko o ka nui o ka wai.
E pōkole, e like me ka hōʻikeʻana ma Fig. 1 ʻO ka OVUMUM OV ma 60 ° C.
Ua hōʻikeʻia nā mea kanu GOG / NZVI a me Nzvi a me Nzvi i hōʻikeʻia e UV-Vispeles UV / Vis Studety LTD No ka nānāʻana i ka mea hoʻokūkū a me ka nui o ka hoʻoiliʻana o ka RGO / NZVI a me NZVI a me NZVI,ʻo Tem-2100 E loiloi i nā hui hana e hiki ke komo i loko o nā mea kanu e lawe i ke kaʻina hana no ka hoʻihoʻiʻana i ka manawa o 4000-600 cm-1). Eia kekahi,ʻo kahi zeta hiki i ka zeta ke loiloi (zetabizer Nano Zs Malvern) i hoʻohanaʻia e aʻo i ka luna o nā mea e pili ana i nā nūpepa synthesized. No ka X-Ray Drifraction e waiho ana i nā nandateral o nā nandedered ʻO ka mea i loaʻa i ka Selpersive X-Ray Spectrometer (Edx) Ua paʻiʻia ka pwder i kahi mea paʻa i kahi mea nāna e paʻa, i kauʻia ma ke keʻena hale. Ua hoʻohanaʻia ka C 1 S Spectrum ma keʻano he 284.58. Ev e hoʻoholo i ka ikehu.
Ua laweʻia nā hoʻokolohua Adsorption e ho'āʻo i ka hana kūpono o ka synthesized RGO / NZVINAD i ka weheʻana i ka Dyxycycline (DC) mai nā hoʻonā Aqueous. Hanaʻia nā hoʻokolohua Adsorption i 25 ML ErnMeyer Flasks ma kahi wikiwiki o 200 RPM) ma ka 298 K. BSL1 E loiloi i ka hopena o ka RGO / NSVI Tosage ma luna o ka hopena Adsorption, nanoMisposites o nā kaupaona likeʻole i hoʻohuiʻia i 20 mL o DC. E aʻo i nā kinetics a me nā adsorption isotherms, 0,05 g o ka adsorbend i hōʻikeʻia i kahi hopena kūpono o ka cd me kaʻike mua (25-100 mg L-1). Ua aʻoʻia ka hopena o ka pH ma ka weheʻana o ka DC ma PH (3-11) a me kahi hoʻololi mua o 50 mg L-1 ma 25 ° C. Hoʻoponopono i ka PH o ka'ōnaehana ma o ka hoʻohuiʻana i kahi liʻiliʻi o ka HCU a iʻole GOSE SOSE (Cronson pH meter, pH ph 25). Eia kekahi,ʻo ka hopena o ka wela o ka hopena o ka hopena o ka hoʻokūkū ma luna o nā hoʻokolohua AdSorption ma ka pae o 25-55 ° C Ua noiʻiʻia. ʻO ka hopena o ka ikaika o ka ikaika o ke kaʻina hana Adsorption e aʻoʻia e ka hoʻohuiʻana i nāʻano likeʻole o ka nacl (1), a me 7), 25) Ua heluʻia ka hoʻolahaʻana o ka adsorption DC i ka hoʻohanaʻana i kahi scolttes duam Uv-Vis Greet, PG. Ka palena o ka pakeneka o dc antibiotics (r%; eq. 1) a me ka nui adsorption o dc, qt, eq. 2 (mg / g) ua anaʻia me ka hoʻohanaʻana i ka hoʻohālikelike aʻe.
kahi o% rʻo ia ka mea lawe dc lawe aku i ka cheelle (%),ʻo COʻo ka DC i ka manawa i ka manawa 0
kahi o ka qe ka nui o dc adsorbed i kēlā me kēia papa hana o ka adsorbente (mg g-1)
Nā kiʻi sem Eia kekahi, aia kekahi mau pulima i loko o ka lau RGO, e hōʻoia ana i ka laweʻana i nā pūʻulu o ka oxygen me ka hoʻihoʻiʻana o ka helu o. Halilima. ʻO kēia mau mea nui i hanaʻia e like me nā pūnaewele no ka hoʻokōʻana i ka hoʻoukaʻana i nā NPS NPS. ʻO nā kiʻi NZV (Fig. 2D-F) hōʻike i ka mea i hoʻopuehuʻia ai nā mea kūʻai aku o nā mea kanu. ʻO ka nui o ka'āpana'āpana i loko o 15-26 nm. Eia nō naʻe, loaʻa i kekahi mau'āina kahi mika leoponopono me kahiʻano o nā pōpoki a me nā lua, hiki ke hoʻonui i ka hiki iā nzvi. I ka wa i hoʻohanaʻia ai ka soma damasus samas Hoʻohālikelike nā hopena me Nzvi Synthesized mai OAK a me Mulberry Wāhi,ʻo ia ka nui o nā poʻe nunui o nā inoa inoaʻole.
Nā kiʻi sem o RGO / NZVI (AC), NZVI (D, E) Nā Kūlana o NZVI / RGO (G) a me Nzvi (H).
Ua aʻoʻiaʻo ka huiʻana o ka mea kanu-Syntheszed RGO / NZVI a me NZVI a me Nzvi Composites e hoʻohana i ka EDX (Fig. 2g, H). Hōʻike i nā haʻawinaʻo NZVI e pili ana i ka carbon (38.29% e ka nui), e like me ka nui. Eia kekahi,ʻo ka hapa nui o ka carbon a me ka oxygen ma mua o ka heleʻana o nā phytochemical mai nā mea kanu i nā mea kūʻai aku. Ua hoʻokaʻawaleʻia kēia mau mea i ka RGO akā ma nāʻano likeʻole: C (39.2 WT%) ʻO ka C: O ka ratio a me ka mea hao i loko o ka RGO / NZVI BET i ka hoʻohanaʻana iā A.ʻO ka WT.% WT.% WT.% WT. wt%) 25. Nataša et al., 2022 i hōʻikeʻia i kahi hui likeʻole a me nā mulberry i hoʻopaʻaʻia i keʻano o ka lau.
ʻO ka morphology o NZVI i nā mea kanu (Fig. S2A ʻO kēia mau hiʻohiʻona granulant a me ka spineclet spelet Kahi mea nānā like i loaʻaʻia e abdfeatad et al. I 2021 I ka wā e hoʻohanaʻia ai ka castor Bean Leaf Lef i hoʻohanaʻia i loko o ka synthesis o nzvi11. ʻO Ruelas TuberosSa Leaf E kiʻi i nā NPS i hoʻohanaʻia e like me ka hōʻemiʻana o ka mea hoʻemi i ka NZVI i kahiʻano spherical me 20 a 40 nm26.
ʻO Hybrid RGO / Nzvi Composite Tom Image (Fig. S2c-D) i hōʻikeʻia e hāʻawi ana i nā mokulele ma nā mokuleleʻo NZGILL Ua hōʻoia houʻia kēia morphor morphor Eia kekahi,ʻo NZVI NPS i loaʻa i kahiʻano spherical me nā'āpana'āpana mai 5.32 a hiki i 27 NM a ua hoʻopiliʻia i ka pā o ka RGO. Ua hoʻohanaʻiaʻo Eucalyptus Leaf Cetract i ka syntheze fe NPS / RGO; Ua hōʻoiaʻia nā hopena o nā mea kanu o ka Brinkles i ka BGO e hoʻomaikaʻi i ka pā o nā NPS iʻoi aku ka nui o nā pper Nā hopena like i loaʻa e kaʻeke et al. 28 I ka manawa i hoʻopiliʻia ai ka hoʻohālikelikeʻana me ka hoʻohanaʻana i nāʻenehana ultrasonic me ka nui o ka nui o ka hao o ka hao hao o ka nui o 17.70 nm.
ʻO ka pākēneka o A. Haliise, Nzvi, E ke, e hele ana, a me nā huiʻo Rgo, a me nā Pego / Nz / Nz / Nz / Nz / Nzvium i hōʻikeʻia ma nā helu. 3a. Hōʻike ka heleʻana o nā hui hana ma nā lau o A. Halimālima ma ka 3336 cm-1, nā mea e pili ana i nā Poyphenos i hanaʻia e ka pakuhi. ʻO nā hui'ē aʻe e like me nā alkanes ma 2918 cm-1, he mau kālā ma 1647 Ma ka laulā, e hōʻike i ka Search NZV Spectra i nā pīni likeʻole e like me ka nui o ka saugsing, akā me kahi kūlana liʻiliʻi. Hōʻikeʻia kahi band ikaika ma 3244 CM-1 i pili me ka stroching chebrations (Phenols) ano13. ʻO ka Stut Spectrum o Gothin e hōʻike i ke alo o nā kūlana kiʻekiʻe he nui ma 1041 cm-1, c = ka st). ʻO kahi hui o C = C i ke kīʻana i nā pōleʻa ma 1619 cm-1, kahi hui nui o Oh Group Ke hoʻohālikelike nei iā RGO a me RGO / NZVI me ka heleʻana,ʻo ka nui o nā pūʻulu o nā oxygen - 1 nalo, e hōʻike ana i ka laweʻana i ka laweʻana i ka hopena o ka oxygengal-found e pili ana i nā hui hana ma Go A. Halilus Extract. ʻO nā kiʻi kiʻi kiʻi hou aku o RGO ma C = C i nānāʻia a puni 1560 a me 1405 cm-1, e hōʻoia ana i ka hoʻemiʻana o ka holoʻana i RGO. Nāʻano likeʻole mai 1043 a 1015 cm-1 a mai 982 a 918 cm-1 i nānāʻia ma ka hoʻopiliʻana o nā mea kanu manu31,32. Weng Et Al., 33: Maikai
A. Fcier Spectrum of Gallium, NZVI, RGO, GGO, GGO, GGOPOSITE RGO / NZVI (A). ʻO ROENTGOGINGY BOGOGENTY RGO, GO, NZVI a me RGO / NZVI (B).
ʻO ka hoʻokumuʻana o RGO / NZVI a me NZVI a me Nzvi composites nui i hōʻoiaʻia e X-Ray Difraction Motterns (Fig. 3b). Ua nānāʻia kahi kiʻekiʻe kiʻekiʻe o FA0 Peak ma 2ɵ 44.5 °, e pili ana i ka kuhikuhiʻana (110) (JCPDS NO. 06-060696) 11. ʻO kekahi Peak'ē aʻe ma 35.1 ° o ka mokulele (311) e pili ana i ka mokulele o ka magnete fe3o4 ʻO ka koho X-Ray o ke heleʻana i kahi hōʻikeʻoi aku ka nui o ka pīkī peak ma 2ɵ 10.3 ° a me kekahi mau pīkī piha o ka pakuhi a me nā kau inoa holoʻokoʻa ma kaʻaoʻao o Go35. ʻO nā hiʻohiʻona hoʻokūkū o RGO a me RGO / NZV i hoʻopaʻaʻia i ka naloʻana o nāʻano a me ka hana o RGO. Eia nō naʻe, ma keʻano o ka hoʻokūkū RGO / NZVIteral, e pili ana i nā Peaks hou e pili ana i ka mokuleleʻo Latting o Fe0 (2000)
ʻO ka zeta hiki ke hiki i ka hopena ma waena o kahi papa inoa inoa inoa inoa i hoʻopiliʻia ma kaʻaoʻao o kahi'āpana a me kahi hopena e hoʻoholo ai i ka pono o ka electrostic Ua hōʻikeʻo ZETA i ka nānāʻana i nā mea kanu lāʻau, e hele, a me nā phova / nzvi, a me ka hōʻikeʻana ma luna o nā mea maikaʻiʻole s1a-c. . ^. Kū pinepineʻia kēlā mau hopena me nā hōʻike he nui e haʻi nei i nā hopena e pili ana i nā helu he nui ma waena o nā mea kūʻai aku ma waena o kēia mau'āpana. Hiki i ka hui pūʻana o RGO a me Nzvi i ka hoʻohuiʻana i keʻano e loaʻa ai nā uku maikaʻi a pēlā paha ke kiʻekiʻe o ka hele a iʻole nzvi wale nō. No laila,ʻo ka phenomenon o ka hoʻoponopono houʻana e alakaʻi i ka hoʻokumuʻana o ka hoʻonohonohoʻana o ka stat rgo / nzvi39. ʻO ka papa maikaʻiʻole o ka hele eʻaeʻia i kahi mea i hoʻopauʻia ma keʻano he mequeous me ka wāʻole, e hana ana i nā kūlana maikaʻi loa no ka pilinaʻana me nzvi. ʻO ka uku maikaʻiʻole e pili ana i ke alo o nā hui likeʻole i ka hoʻopiʻi Melon, e hoʻopaʻa ana i ka piliʻana ma waena o ROG a me nā Polokalamu 'Olz / NZVI. Hiki i kēia mau mea kanu ke hana ke hana like me ka cappking a i nā mea hana, e pale ana i ka hoʻohuiʻana o nā nanooporic a pēlā hoʻi kā lākou kūpaʻa.
Ua hoʻoholoʻia ka huiʻana a me nā mea kūʻai aku o ka NZVI a me RGO / NZVI / NZVI. 4). Ua hōʻikeʻia ka noiʻi XPS i hōʻikeʻiaʻo RGO / NZVITITE BOGOTITITE i ka mea nui o nā mea e pili ana i nā mea o nā mea c, o, a me ka fe, cesc. 4f-h). 4f-h). 4f-h). 4f-h). 4f-h). ʻO nā C1S Spectrum heʻekolu mau pīkī ma 284.59 ev, 286.21 ev a me 288.21 EV a me 288.21 EV Ua hoʻokaʻawaleʻia nā O1s Spectrum iʻekolu mau pīkoi, e hui pū me 531.17 Eia nō naʻe,ʻo nā peaks ma 710.43, 714.57 a me 724.7, F + 3, FE + 3 ʻO nā XPS Spectra o NZVI (Fig. 4C-e) i hōʻike i nā Peaks no nā mea e pili ana i nā mea no keʻano c, o, a me ka. Peaks ma 284.77, 286.25, a me 287.62 e hōʻoia i ka heleʻana o CC, e pili ana i ka CC, e pili ana i ka CC, e pili ana, a me CO, a me CO, a me CO, a me CO, a laila. Ua hoʻopiliʻia ka O1s Spectrum iʻekolu mau pīkī c-o / iron carbonate (5319.19.19 Ua hōʻikeʻia ka pīkī ma 719.6 i ka manawa o Fe0,ʻoiaiʻo FEOH e hōʻike ana i nā peʻa ma ka 717.3
XPS Studies o NZVI a me BGO / NZVI BETPOSETIE, A, B). Piha piha o nzvi c1s (c), fe2p (d), a me ka o1s (e), a me ka b.s (h).
ʻO ka N2 Adorption / Desorption isotherm (Fig. Eia kekahi, ua hoʻonuiʻia ka wahi kiko'ī (sbet. Hiki ke weheweheʻia kēia hopena ma ka emiʻana o nā waiwai o NZVIN ma hope o ka maka makapō a me ka hoʻemiʻana i ka'āpana o nā hui. Eia kekahi, e like me ka hōʻikeʻana ma Fig. 5c, ka nui o ka nui o ka pore ʻO kēia hopena i kaʻaeʻia me El-Menaem et al. 45.
No ka loiloi i ke hikiʻana i ka hoʻolahaʻo Adsorption e wehe iā DC ma waena o nā bogo / nzvi composites a me keʻano maʻamau Hoʻolālā i nā hopena [25]. -100 MG L-1] ma 25 ° C. Ua hōʻike nā hopena i ka maikaʻi o ka hoʻopauʻana (94.6%) o ka bgo / nzvi composite kiʻekiʻe (90%) ma kahi haʻahaʻa haʻahaʻa (25 mg L-1). Eia naʻe, i ka wā e hoʻonuiʻia ai ka hoʻokūkū hoʻomakaʻana i ka 100 mg L-1, ka hopena o keʻano he nui o ka inoaʻo RGO / NZVI Ma ka mea i kū'ēʻia,ʻo RGO / NZVI i kahi kiʻekiʻe o DC a hiki i ka hopena o RGO / NZVI, ma keʻano he nui o RGO / NZV Eia kekahi, ma Fig. Ua hōʻikeʻo 6b i ka hikiʻana o ka adsorption o ka RGO / NZVI a me Nzvi a me Nzvi -1.1 a 28.73 mg g-1. No laila,ʻaʻole i hoʻoponoponoʻia ka wikiwiki DC Femival me ka loaʻaʻana o ka DC mua,ʻo ia ka mea i kaupalenaʻia e ka hoʻolahaʻana o DC i ka hoʻoponoponoʻana. No laila, hiki ke hoʻopauʻia mai kēia mau hopena i loaʻa ka maikaʻi o nā RGO / NZVI i kahi kiʻekiʻe o RGO / NZVI i keʻano o ka mea lawe aku.
ʻO ka pono o ka hoʻopauʻana a me ka pono Adsorption o DC AdSorption no ka RGO / NZVI a me NZVI a me NZVI (A, B, B. Ma ka hikiʻana o Adsorption a me DC Celeval i ka maikaʻi o RGO / NZVI (C) [CO = 06 °.
ʻO SPEFS PH ka mea koʻikoʻi koʻikoʻi i ke aʻoʻana o nā kaʻina hana adsorption,ʻoiai e pili ana i keʻano o ka'ōlelo o ka hoa noi Ua laweʻia ka hoʻokolohua ma kahi o 25 ° C me kahi ADSORBEND DOSE (0.05 G) a me kahi hana mua o 50 MG L-1-11). Wahi a kahi loiloi palapala palapala leka uila Ma muli o kahi hopena, nā hana likeʻole o DC a me nā hana e pili ana i ka papa o RGO / NZROTER, ZCH (DCH0-). Ma muli o kahi hopena, nā hana likeʻole o DC a me nā hana e pili ana i ka papa o RGO / NZROTER, ZCH (DCH0-). Винрата кичия кИла трукут в кстидеорелет в тидеовоимпоктокимоктовоия сэгра вичимоля С4 Иствовски тка ТИла та та та бе товонов "" Иуганитеббе на Аниный (Dch- или DC2-) пРи PH 7,7. Ma muli o kahi hopena, nā hana likeʻole o DC a pili i nā hana e pili ana i ka papa o ka papa o ka RGO / NZVI pono a hiki ke noho ma keʻano o nā ciations, zisticters, a me nā mea hoʻi; Nohoʻo DC Molecule e like me kahi cation (dch3 +) ma ph <3.3; iniko (dch20) 3.3 <ph <7.7 a me anionic (dch- a dc2 paha-因此, DC My @ wale-nzevi / nzevi 复合材料表面 的 形式存在, 形式存在, 形式存在, 形式存在, 形式存在, 或, 或, 或, 或, 或 dc2 7.3 dch (dch (dch (dch (dch 7.3.因此: hohonu / 种 功能 和和和 和 会表面 相关, 在 阴离子两 阳离子形式,3 在, 阳离子, 阳离子 (DCH (DCH (DCH (DCH (DCH (DCH或 DC2-) 在 ph 7.7. Слледоительна N. Скачать вТ micвволатиона циновна та дкт3 +). No laila, he mau hana like o DC a pili ana i nā papa hana e pili ana i ke aniani o nā coactual. Он Сутаплвау3 твиттер-Мон 3 7 (ALLLL) Aia ia he zwitterion (dch20) ma 3.3 <ph <7. 7 a me kahi anioni (dch- a iʻole dC2-) a iʻole dC2-)Me ka hoʻonuiʻana i ka PH mai 3 a 7, i ka nui o ka hoʻolahaʻana a me ka maikaʻi o ka DC / G (85%). Eia nō naʻe, e like me ka hoʻonuiʻiaʻana o ka ph i 9 a 11, ua hōʻemi ka pono adsorping a me ka hoʻohanaʻana i ka hoʻopauʻana o ka ea. Me ka hoʻonuiʻana i ka PH mai 3 a 7, DCS nui i loaʻa i keʻano o nā zwitterions, i hana houʻia e nā mea koho balota. E like me ka hoʻonuiʻana o ka ph ma luna o 8.2, ua hoʻopiʻi maikaʻiʻia kaʻaoʻao o ka adsorbente, no laila ua emi ka hopena o ka adsortatic Hōʻike kēia tylock i kēlā me kēia adsorption ma Rgo / Nzvi Bouposites, e hoʻohālikelike ana nā hopena o RGO / NZVI ma lalo o Acaidis
ʻO ka hopena o ka mahana ma luna o ka hoʻolahaʻana o ka hoʻoponoponoʻana o kahi hoʻonā o kahi mea i laweʻia i ka DC i laweʻia ma (25-55 ° C). Hōʻike ka kiʻi ma ka hopena o ka hoʻonuiʻana o ka mahana ma ka hopena o nā DC antibatinity o RGA / NZVI, a me 13.9 Mg / G. ,ʻoluʻolu. ʻO kēia hōʻemi koʻikoʻi paha ma muli o ka hoʻonui nuiʻana i ka ikehu o ka hale o nā DC
Ka hopena o ka mahana ma ka hoʻohanaʻana i ka hana kūpono a me ka hana e pili ana i ka CD ma RGO / NSVI = 7 MG) = 50 mg l-1, pH = 7, t = 25 ° C] (25 ver.
ʻO ka hopena o ka hoʻonuiʻana i keʻano o ka hoʻohuiʻana o ka adsorbente adsorbente RGO / NZVI mai 0,01 g a 0,07 g on the cup. 7b. Ka hoʻonuiʻana i ka loaʻaʻana o ka adsorbented i alakaʻiʻia i kahi hōʻemi i ka nui o ka hoʻolahaʻana mai ka 33.43 mg / g. Eia naʻe, me ka hoʻonuiʻana i ka hoʻolaha hoʻolaha mai 0.01 G a 0,07 g, e pili ana i kahi hoʻonui i ka nui o nā keʻena ikaika ma ka hale kiaʻi.
ʻO ka hopena o kaʻike muaʻana ma luna o ka pono adsorption a me ka hoʻopauʻana i ka hoʻopauʻana [25-100 MG L-1, 25 ° H. I ka hoʻonuiʻiaʻana o ka pono mua mai 25 mg l-1 a 100 mg L-1, e hōʻemi ana i ka helu o ka RGO / NZVI. . ^. ʻO nā mea hoʻolaha nui nui o DC49. Ma kaʻaoʻao'ē aʻe, ua hoʻonuiʻia ka meaʻoi aku ka nui o kaʻike mua, ua hoʻonuiʻia ka hikiʻana i ka Adsorpation ma 9.4 mg / g a hiki i ka pono. ʻO kēia hopena i hikiʻole ke hoʻonui i ka hoʻonuiʻana i ka ikaika o ka hoʻokele muaʻana ma mua o ka paleʻana o ka DC ma mua o ka DC Id
E kamaʻilio i ka manawa a me nā loiloi kinetic i manaʻo e hoʻomaopopo i ka manawa equilibrium o ka adsorprit. ʻO ka mua,ʻo ka nui o DC ADC ADSORBED i ka wā o 40 mau minuke mua o ka manawa e pili ana i ka huina o ka huina o ka huina ʻOiai e pili ana i nā mollucules o DC i ka hoʻonāʻana i ka hoʻokūkūʻana iā lākou e wikiwiki i ka neʻeʻana i ka maka o ka RGO / NZVI. Ma hope o 40 min, ua hoʻonui pinepineʻiaʻo DC Adporption a lohi a maloʻo a hiki i ke kaulike ma hope o 60 min (Fig. 7d). Mai ka nui o kahi kūpono i hōʻikeʻia i loko o nā minuke 40 mua, e liʻiliʻiʻia nā mea e loaʻa ai nā mollecules me nā molena dc e loaʻa nā moleki. No laila, hiki ke hōʻemiʻia ka helu AdSorption
E hoʻomaopopo maikaʻi i nā kinikona adsorption, laina plots o ka kauoha mua o Pseudo (Fig. 8C) Mai nā parameter i loaʻa mai nā haʻawina kinetic (papa S1), e lilo ia i meaʻoi aku ka nui o ka pseudosecond no ka weheweheʻana i ka R2 ma mua o nāʻanoʻelua Aia kekahi like me ka like ma waena o nā mea e pili ana i nā mea i kohoʻia (QE, Cal). ʻO ka papa helu Pseudo-ʻelua a me nā waiwai hoʻokolohua (QE, Exp. E like me ka hōʻikeʻana ma ka papa 1, nā waiwai o ka α (ʻoi aku ka nui o ka helu AdSorption ma mua o ka helu AdSorp ma mua o ka ADSORPPT . ^.
Nā kiʻinaʻo Linear Adsorption Kinutic Plots o Pseudo-lua lua (A)
ʻO nā noiʻi o nā mea kōkua adsorption e kōkua i ka hoʻoholoʻana i ka hikiʻana o ka Adsorption o ka AdSorbence Ua heluʻia ka nui o ka pono adsorption kiʻekiʻe e hoʻohana ana i ka langmuir is themormism ʻElua mau mea'ē aʻe i hoʻohanaʻiaʻo ITOtherm Models i nā hiʻohiʻona freundlich a me nā hiʻohiʻona Tamkin. ʻOiaiʻaʻole i hoʻohanaʻia ka hiʻohiʻona freundlich e helu i ka hiki ke hoʻomaopopo i ka hana adsorbles e kōkua i ka adsorbleneous
Nā kiʻi 9A-C Hōʻike i nā laina laina o ka langsur, ferindlich, a me nā modem likeʻole, a me nā modem modin, a me nā mea hoʻohālike. Ua heluʻia nā waiwai R2 mai ka freundliphich (Fig. 9A) a me ka lapalapaʻo Frendomlich ʻO ka nui o kaʻike nui loa Eia kekahi,ʻo ka waiwai i heluʻia o ka hoʻokaʻawaleʻana o ka hoʻokaʻawaleʻana o ka hoʻokaʻawaleʻana (RL) ma waena o 0 a 1 (0.097) A iʻole,ʻo ka mea i hoʻokaʻawaleʻia i ka manawa (N = 2.756) hōʻike i kahi makemake no kēia kaʻina hana. Wahi a keʻano o ka laina laina o ka temkin isobinm (Fig. 9C) ʻOiaiʻo ka adsorption kino pilikino e hoʻopili pinepineʻia e nā mea kanu consal festas e hoʻohana i nā mea e pili ana i kēia manawa i nā mea edies adsorption haʻahaʻa [56, 57].
Frehunderlich (a), langsur (b) Plot of the van't whiff e hoʻohālikelikeʻia no ka adsorption dc / nzvi composites (d) [25-100 m / 25-15 ° C a does.
No ka loiloiʻana i ka hopena o ka hoʻololiʻana o ka hopena o ka hopena o ka DC i kahi hoʻololi o RGO / NΔSo. 3 a 458.
kahi <(k} _ {() = \ (\ frac {{cy. R a me Rt ka mea maʻamau a me ka wela o ka haunaele a me ka hoʻonuiʻana i ka hoʻolahaʻana, e pili ana. ʻO ka hoʻolālāʻana iā LN Ke kū'ē iā 1
Hōʻike ka waiwai Δh Δh i hōʻikeʻia e loaʻa ke kaʻina hana. Ma kaʻaoʻao'ē aʻe,ʻo ka waiwai Δh i loko o ke kaʻina hana adspulation kino. ʻO nā waiwai δG ΔG ma ka papaʻaina 3 e hōʻike ana he mea hiki ke loaʻa a hiki i keʻano. ʻO nā waiwai maikaʻiʻole o ΔS e hōʻike ana i kahi kauoha kiʻekiʻe o nā molekula adsorbed molecules ma ka pahu wai (papa 3).
Pākuʻiʻia ka papaʻaina 4 Ua maopopo ia ua loaʻa i ka prgo / ncvi compositite i ka nui o ka lehulehu a iʻole he mea hoʻolaha e hoʻolaha ana no ka weheʻana o DC Antifatitics mai ka wai. Eia kekahi,ʻo ka adsorption o RGO / NZVI GOPPOSTIES kahi kaʻina wikiwiki me kahi manawa kūpono o 60 min. ʻO nā waiwai a nā adsorption maikaʻi loa o nā bgo / nzvi composites e weheweheʻia e ka hopena synergistic o RGO a NZVI.
Nā kiʻi 10A, B i ke kiʻiʻana i ka mea hana hoʻokūkū no ka weheʻana o DC Antibiotika e ka RGO / NZVI a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me Nzvi a me NZVI. Wahi a nā hopena o nā hōʻike ma ka hopena o ka hoʻohuiʻana, me ka he 7 a 7,ʻo ia ka mea i hanaʻia ma ka zowslication ma 3 a 4, No laila,ʻaʻole i loli ka loli ma ka waiwai PH i ke kaʻina hoʻolaha i ka wā AdSHele. Ma hope mai, hiki ke kāohiʻia ka mīkini adsorption e nā mea e pili ana i nā mea e pili ana i ka hydrogonication, a me πroophobic, a me Π. Ua kaulanaʻo ia eʻikeʻia nā mea hana a Aromanis o nā mea e pili ana i nā papa o nā mea i hoʻopaʻaʻia e ka nui o ka criphoned e like me ka ikaika o ka hoʻokele nui. ʻO keʻano he mea e like me ka mea e like me ka cripher me ka cigphene me ka nui loa ma ka 233 NM no ka inoa-π * π *. E pili ana i ka heleʻana o nā apo i nā apo i loko o ka mole o ka dc adorsate / nzvi composites. Eia kekahi, e like me ka hōʻikeʻana ma Fig. Ua hanaʻia nā haʻawina 10b, e aʻoʻia e aʻo i ka hoʻopiliʻana o ka mole o ka bto / nzvi composites me dc 10b. Ua nānāʻia kahi Peak hou ma 2111 cm-1, e pili ana i ka hoʻopiliʻana i ka hana o ka C = C i hōʻike i keʻano o ka papa o ka papa o ka c = cgo / nzvi. ʻO nā poʻe'ē aʻe'ē aʻe mai 1561 a 1548 cm-1 a mai 1399 e pāʻani ana i ka nui o nā crispne a me nā mea nui o ka craphenic a me nā mea nui o ka craphenic Ma hope o ka hoʻolahaʻana o DC Adonstp me kekahi o nā pūʻulu o nā oxygen-pohia, e like me ka nui o nā aniani he 3270 cm-1, kahi i manaʻo ai ka mea hana hydroge. No laila, e pili ana i nā hopena, DC AdSorption ma ka BGO / NZvi Composite ma muli o ka nui o nā pilina a me nā h-komo.
Rational Mechanism o Adsoriotic o DC Antibiotics e RGO / NZVI a me NZVI a me NZVI a me NZVI. FTIR ADSORPLE SPECTRA o DC ma RGO / NZVI a me NZVI (B).
ʻO ka ikaika o ka piliʻana o ka poʻe noho i ka NZVI ma 3244, 1615, 1546, a me 1011. Eia nō naʻe,ʻo kēia haʻahaʻa haʻahaʻa haʻahaʻa o ka laweʻana i nā mea iʻikeʻia i nā mea iʻikeʻia i ka loli nui o ka hoʻolahaʻana o Phytoysthenical (NZVI) Wahi a kekahi o kekahi noiʻi DC Celeval me NZVI71, i ka wā e hele aiʻo Nzvi i ka H2O, e hoʻohanaʻia e ka Hydrogen. ʻO ka hope loa, loaʻa kekahi mau conic i loaʻa i nā electrons mai ka hydrogen ikaika, e hopena ana i -c = n a me -c = c-
POST manawa: Nov-14-2022